4.5 Review

Recent Advances of Catalytic Enantioselective Heck Reactions and Reductive-Heck Reactions

期刊

CHINESE JOURNAL OF CHEMISTRY
卷 39, 期 3, 页码 710-728

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202000464

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Heck reaction; Asymmetric catalysis; Palladium; Nickel; Reductive Heck reaction

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This review focuses on recent development of catalytic asymmetric Heck reaction and reductive Heck reaction, covering intermolecular and intramolecular versions since 2011. The article is organized in terms of the catalysts and olefin substrates, providing a clear structure for readers.
Heck reaction is one of the most important carbon-carbon bond forming reactions with wide applications in organic synthesis. Considerable advances of enantioselective Heck reaction have been achieved in the past decades. This review focuses on recent development of catalytic asymmetric Heck reaction and reductive Heck reaction, which covers intermolecular and intramolecular versions since 2011. The article is organized in terms of the catalysts and olefin substrates.

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