期刊
CHINESE JOURNAL OF CHEMISTRY
卷 39, 期 1, 页码 143-148出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202000407
关键词
Electrosynthesis; Palladium‐ catalyzed; Cross coupling; Amination; Carbazoles
资金
- National Natural Science Foundation of China [21520102003]
- Hubei Province Natural Science Foundation of China [2017CFA010]
The synthesis of carbazoles was achieved through electrochemical Pd-catalyzed intramolecular C-H amination of 2-amidobiaryls under mild conditions, without the need for external chemical oxidants. The resulting carbazoles are easily scalable and modifiable, providing a simple and sustainable method for their construction compared to previous techniques.
Main observation and conclusion The synthesis of carbazoles based on the electrochemical Pd-catalyzed intramolecular C-H amination of 2-amidobiaryls through oxidative cross coupling has been achieved under mild reaction conditions. The reaction can be carried out in undivided cell without the addition of external chemical oxidant. Besides good functional group compatibility, the desired carbazoles can be scaled up and modified easily. Compared with previous methods, this protocol affords a simple and sustainable avenue for the construction of carbazoles.
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