期刊
CHINESE CHEMICAL LETTERS
卷 32, 期 4, 页码 1491-1496出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2020.09.029
关键词
N/O co-doped; Ultramicroporous; Metal-organic frameworks; Porous carbons; Supercapacitors
资金
- National Natural Science Foundation of China [21501135, 21875165]
- Fundamental Research Funds for the Central Universities
- Recruitment Program of Global Experts of China
A new nonporous Zn-based metal-organic framework (NPMOF) synthesized from a high-nitrogen-containing rigid ligand was converted into porous carbon materials with high N/O contents through direct carbonization, showing excellent supercapacitive performance and stability. This simple preparation method opens up a new pathway for producing high-quality energy storage materials.
A new nonporous Zn-based metal-organic framework (NPMOF) synthesized from a high nitrogen-containing rigid ligand was converted into porous carbon materials by direct carbonization without adding additional carbon sources. A series of NPMOF-derived porous carbons with very high N/O contents (24.1% for NPMOF-700, 20.2% for NPMOF-800, 15.1% for NPMOF-900) were prepared by adjusting the pyrolysis temperatures. The NPMOF-800 fabricated electrode exhibits a high capacitance of 220 F/g and extremely large surface area normalized capacitance of 57.7 mu F/cm(2) compared to other reported MOF-derived porous carbon electrodes, which could be attributed to the abundant ultramicroporosity and high N/O co-doping. More importantly, symmetric supercapacitor assembled with the MOF-derived carbon manifests prominent stability, i.e., 99.1% capacitance retention after 10,000 cycles at 1.0 A/g. This simple preparation of MOF-derived porous carbon materials not only finds an application direction for a variety of porous or even nonporous MOFs, but also opens a way for the production of porous carbon materials for superior energy storage. (C) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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