4.3 Article

Do Particles Interact Electronically? -Proof of Interparticle Charge-transfer Excitation between Adjoined Anatase and Rutile Particles

期刊

CHEMISTRY LETTERS
卷 50, 期 1, 页码 80-83

出版社

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.200636

关键词

Energy-resolved distribution of electron traps; Reversed double-beam photoacoustic spectroscopy; Interparticle charge-transfer excitation

资金

  1. MEXT KAKENHI [15H022010, 18H039230]
  2. China Scholarship Council Program [201704910878]

向作者/读者索取更多资源

Experimental evidence shows that interparticle spatial overlapping of orbitals leads to interparticle charge-transfer excitation at an anatase-rutile interface, which can help clarify the relative band position of metal-oxides and the mixture homogeneity of mixture samples.
Here, we report experimental evidence of interparticle spatial overlapping of orbitals to result in interparticle charge-transfer excitation (ICTE) at an anatase-rutile interface which is expected to be applicable to clarify the relative band position of metal-oxides and mixture homogeneity of mixture samples measured by reversed double-beam photoacoustic spectroscopy.

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