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Synthesis of 1,8,13-Substituted Triptycenes

期刊

CHEMISTRY LETTERS
卷 50, 期 1, 页码 39-51

出版社

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.200600

关键词

Triptycene; Diels-Alder reaction; Aryne

资金

  1. JSPS KAKENHI [JP18H02557, JP18H04418, JP18H04624, JP20H04780, JP20K21198, JP20K15283]
  2. NAGASE Science Technology Foundation
  3. Asahi Glass Foundation
  4. Qdai-jump Research Program Wakaba Challenge at Kyushu University
  5. IRCCS Fusion Emergent Research Program

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This paper summarizes the syntheses of 1,8,13-substituted triptycenes, highlighting the interesting structural features of their C-1,8,13 substituents and the open faces of the molecule for various interactions and applications.
Triptycene is an aromatic compound with D-3h symmetry, where three benzene rings are fused to a bicyclo[2.2.2]octatriene skeleton. 1,8,13-Substituted triptycenes exhibit interesting structural features: the C-1,8,13 substituents and the bridgehead C-9 position are located in the same plane. Three faces of the molecule are open for interesting interactions and applications. This paper summarizes the syntheses of 1,8,13-substituted triptycenes.

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