期刊
CHEMICAL REVIEWS
卷 121, 期 14, 页码 8948-8978出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.0c00811
关键词
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资金
- National Natural Science Foundation of China [21502110]
- Natural Science Foundation of Shaanxi Province [2019JQ-323]
- young top-notch talent of Special Support Plan for High-Level Talents in Shaanxi Province
- 111 project [B14041]
- Fundamental Research Funds for the Central Universities [GK201903039]
Gold carbenes are highly active in homogeneous gold catalysis, facilitating various transformations including C-H/X-H insertions, cyclopropanations, and 1,2-migrations. While 1,2-migrations onto gold carbene centers have received less attention compared to other reactions, they have the potential to be a powerful tool for constructing molecular complexity rapidly and simply.
Gold carbenes are highly active intermediates in homogeneous gold catalysis, enabling a large array of transformations such as C-H/X-H insertions, cyclopropanations, and 1,2-migrations. Unlike C-H/X-H insertions and cyclopropanations, 1,2-migrations onto gold carbene centers seem to be attracting less attention. There has been no comprehensive review focusing on this topic, even though this chemistry has become a powerful tool for the rapid and simple construction of molecular complexity. This review provides comprehensive and critical information on the 1,2-migrations onto gold carbene centers, drawing a preliminary conclusion on the migratory aptitude of various groups. The review is divided into several parts according to the kind of carbene precursors.
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