期刊
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
卷 158, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cep.2020.108199
关键词
Reactive distillation; Catalyst layer efficiency factor; Multiphase flow; Multicomponent reactive transport; Direct hydration of cyclohexene
资金
- National Natural Science Foundation of China [21808037, 21706034]
- Natural Science Foundation of Fujian Province of China [2020J01515]
- open foundation of State Key Laboratory of Chemical Engineering [SKL-ChE-18B02]
Reactive distillation is an important intensification technology to overcome the unfavorable equilibrium conversion for the direct hydration of cyclohexene. In this work, a multiphase flow and multicomponent reactive transport model in the catalyst layer was established. By virtue of the model, the influences of structural parameters of the catalyst layer, physical parameters of two-phase fluid and reaction conditions on the catalyst layer efficiency factor were investigated. It was found that physical parameters of two-phase fluid can influence the two-phase distribution, thus affecting the catalyst layer efficiency factor. The catalyst layer efficiency factor decreases slightly with the rise of solubilities of cyclohexene and cyclohexanol, although concentration of cyclohexanol and reaction conversion can be improved by the addition of co-solvents. Furthermore, it was found that the catalyst layer efficiency factor is independent on structural parameters approximately. Therefore, the design of process-specific catalytic packings has remarkable difference between miscible and immiscible reaction systems.
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