期刊
CHEMCATCHEM
卷 12, 期 23, 页码 5903-5906出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202001315
关键词
rhodium; silver; C-H activation; sulfoxonium ylides; naphthol-indole
资金
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- National Natural Science Foundation of China [21372250, 21121062, 21302203, 20732008, 21772037, 21772226, 21861132014, 91956115]
Synthesis of naphthol-indoles starting from easily available 1,3-diynes and sulfoxonium ylides via Rh-III-catalyzed C-H activation/hydroamination cascade process in a one pot manner has been developed. The reaction proceeds through a Rh-III-catalyzed areneorthoC-H activation and silver-catalyzed hydroamination cascade to afford a variety of C2 position functionalized indoles in good yields with broad substrate scope and good functional group tolerance.
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