期刊
CATALYSIS TODAY
卷 366, 期 -, 页码 48-56出版社
ELSEVIER
DOI: 10.1016/j.cattod.2020.09.033
关键词
Niobia; Silica; Magnetite nanoparticles; Core-shell magnetic nanocomposite; Glucose; HMF; Catalytic dehydration
资金
- UEFISCDI [PN-III-P4-ID-PCE-2016-0533, 116/2017]
Niobia-based magnetic nanocomposites were prepared by covering magnetite nanoparticles cores with Nb2O5 or Nb2O5-SiO2 shells in a two-step procedure. The catalytic performances were closely related to the nature of the supported niobia phases, influenced by the niobia content and preparation route. The high selectivity to HMF was linked to the large pseudohexagonal niobium oxide phase, while the catalytic activity was associated with small nanoparticle size.
Niobia-based magnetic nanocomposites were prepared by covering magnetite nanoparticle cores (Fe3O4, MNP) with either Nb2O5 or Nb2O5-SiO2 shells using a two-step procedure. In the first step magnetite nanoparticles were prepared by the coprecipitation method. The second step involved their coverage with either Nb2O5 shells, through a precipitation method, or with Nb2O5-SiO2 shells, through a sol-gel protocol followed by precipitation in the presence of the CTAB surfactant. The obtained materials were exhaustively characterised by X-ray diffraction, Mossbauer spectroscopy, magnetic measurements, ICP-OES, DRIFT and Raman spectroscopy, and CO2 - and NH3-TPD measurements, and investigated for glucose dehydration to HMF. The catalytic performances were directly correlated to the nature of the supported niobia phases, which, in turn, has been dictated by the niobia content and the preparation route. The high selectivity to HMF was correlated with to the large pseudohexagonal niobium oxide (TT-Nb2O5) phase while the catalytic activity was directly correlated to the small nanoparticles size. A proper combination of these features led to an optimum catalytic system for the selective production of HMF through glucose dehydration. A third important feature making the developed catalyst promising is its magnetic property, ensured by the magnetite nanoparticles core. This allowed its easy separation from the reaction products.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据