期刊
ASTRONOMY & ASTROPHYSICS
卷 643, 期 -, 页码 -出版社
EDP SCIENCES S A
DOI: 10.1051/0004-6361/202039251
关键词
astrochemistry; ISM: molecules; ISM: individual objects: TMC-1; line: identification; molecular data
资金
- Ministerio de Ciencia e Innovacion [AYA2016-75066-C2-1-P, RyC-2014-16277]
- ERC [ERC-2013-Syg-610256-NANOCOSMOS]
Using the Yebes 40m radio telescope, we report the detection of a series of seven lines harmonically related with a rotational constant B-0 = 1295.81581 +/- 0.00026MHz and a distortion constant D-0 = 27.3 +/- 0.5Hz towards the cold dense cloud TMC-1. Ab initio calculations indicate that the best possible candidates are the cations HC5NH+ and NC4NH+. From a comparison between calculated and observed rotational constants and other arguments based on proton affinities and dipole moments, we conclude that the best candidate for a carrier of the observed lines is the protonated cyanodiacetylene cation, HC5NH+. The HC5N/HC5NH+ ratio derived in TMC-1 is 240, which is very similar to the HC3N/HC3NH+ ratio. Results are discussed in the framework of a chemical model for protonated molecules in cold dense clouds.
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