期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 272, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2020.118982
关键词
Conjugated microporous polymer; Phenothiazine core; Charge transfer; Photocatalysis; Organic transformations
资金
- National Science Foundation of China [21674129, 51873232, 21636010]
- Fundamental Research Funds for the Central Universities of Central South University [2018zzts108]
- Open Sharing Fund for the Largescale Instruments and Equipments of Central South University [CSUZU1930, CSUZC201927]
Task-specific design and construction of conjugated microporous polymers (CMPs) for classic organic transformation is highly significant but challenging. Herein, we report strategy to promote charge transfer in CMPs using phenothiazine unit as a core and commonly used building blocks (carbazole/benzene) as the linker. Featuring by wide visible-light absorption, narrow optical bandgap, and facilitated charge transfer, phenothiazine-core CMPs exhibited superior photocatalytic performance towards Ugi-type reaction and aerobic selenation of indoles compared with those phenothiazine-free counterparts and commonly reported photocatalysts. Furthermore, the photocatalytic enhancement achieved in the designed CMPs system represents a substantial advance and verifies the viability of a simple strategy to tailor the photophysical properties of CMPs, which may facilitate the design of new photocatalysts.
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