期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 6, 页码 2861-2865出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202012322
关键词
anodes; dendrite-free; MXene layer; zinc-ion batteries
资金
- NSFC [51822205]
- Ministry of Science and Technology of China [2019YFA0705600]
- Natural Science Foundation of Tianjin [18JCJQJC46300]
In this study, an ultrathin and uniform MXene layer was assembled on the surface of zinc anodes using an in situ spontaneously reducing/assembling strategy. The integrated MXene layer reduced the zinc nucleation energy barrier and provided a more uniformly distributed electric field, resulting in low voltage hysteresis and excellent cycling stability with dendrite-free behaviors in zinc-ion batteries.
Metallic zinc is a promising anode candidate of aqueous zinc-ion batteries owing to its high theoretical capacity and low redox potential. However, Zn anodes usually suffer from dendrite and side reactions, which will degrade their cycle stability and reversibility. Herein, we developed an in situ spontaneously reducing/assembling strategy to assemble a ultrathin and uniform MXene layer on the surface of Zn anodes. The MXene layer endows the Zn anode with a lower Zn nucleation energy barrier and a more uniformly distributed electric field through the favorable charge redistribution effect in comparison with pure Zn. Therefore, MXene-integrated Zn anode exhibits obviously low voltage hysteresis and excellent cycling stability with dendrite-free behaviors, ensuring the high capacity retention and low polarization potential in zinc-ion batteries.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据