期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 3, 页码 1433-1440出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202012550
关键词
BiVO4 photoanode; NiFe-MOFs; OER; oxygen vacancy; stability
资金
- NSFC [21725602, 21938002, 21671062, 21776064]
- Innovative Research Groups of Hunan Province [2019JJ10001]
- Science and Technology Planning Project of Hunan Province [2019RS3010]
- Hunan Provincial Innovation Foundation for Postgraduate [CX2018B193]
The use of NiFe-MOFs coating on oxygen-vacancy-rich BiVO4 to form a core-shell structure has been shown to enhance the photocurrent density and stability of the photoanode.
The introduction of oxygen vacancies (Ov) has been regarded as an effective method to enhance the catalytic performance of photoanodes in oxygen evolution reaction (OER). However, their stability under highly oxidizing environment is questionable but was rarely studied. Herein, NiFe-metal-organic framework (NiFe-MOFs) was conformally coated on oxygen-vacancy-rich BiVO4 (Ov-BiVO4) as the protective layer and cocatalyst, forming a core-shell structure with caffeic acid as bridging agent. The as-synthesized Ov-BiVO4@NiFe-MOFs exhibits enhanced stability and a remarkable photocurrent density of 5.3 +/- 0.15 mA cm(-2) at 1.23 V (vs. RHE). The reduced coordination number of Ni(Fe)-O and elevated valence state of Ni(Fe) in NiFe-MOFs layer greatly bolster OER, and the shifting of oxygen evolution sites from Ov-BiVO4 to NiFe-MOFs promotes Ov stabilization. Ovs can be effectively preserved by the coating of a thin NiFe-MOFs layer, leading to a photoanode of enhanced photocurrent and stability.
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