期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 24, 页码 5783-5787出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202001020
关键词
Phosphorylation; C(sp(3))− H bonds; iron catalysts; air; β -ketophosphine oxides
资金
- Science and Technology Planning Project of Guangdong Province [2017A010103044]
- Technology Plan of Guangdong Province [2019A050510042]
- Guangdong Basic and Applied Basic Research Foundation [2019B1515120023, 2019B1515120035]
- Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province [2016kf07]
- (South China University of Technology)
A C(sp(3))-H phosphorylation has been achieved via the iron-catalyzed cross-coupling reactions between 1,3-dicarbonyl compounds and P(O)-H compounds involving C-C bond cleavages with air as the oxidant. This transformation provides a straightforward way to construct C(sp(3))-P bonds, leading to the formation of beta-ketophosphine oxides in up to 93% yield with good functional group tolerance.
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