期刊
ADVANCED FUNCTIONAL MATERIALS
卷 31, 期 4, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202006533
关键词
bimetal; electrocatalysis; oxygen reduction reaction; zinc-air battery
类别
资金
- National Natural Science Foundation of China [21703149, 11974004, 51622208, 51872193, 5192500409]
- National Key Research and Development Program of China [2018YFA0306102]
- Natural Science Foundation of Jiangsu Province [BK20190827, BK20181168]
This study identifies the critical role of bimetal sites in boosting oxygen reduction activity, confirming their potential feasibility in practical applications.
Zinc-air battery is of great interest but its wide-ranging application is impeded by the sluggish cathodic reactions, especially the oxygen reduction reaction. Despite blooming development in the past decades, achieving further breakthroughs in the activity improvement still appears challenging. Herein, the critical role of bimetal sites in boosting oxygen reduction activity is identified with the combination of theoretical calculations and electrochemical experiments. Density functional theory calculations suggest the elongation of O-O bond over the dual-atom system, which is beneficial to its following dissociation and thus enhances the efficiency of the reaction. The proof-of-concept electrocatalyst experimentally delivers a half-wave potential of 0.92 V versus reversible hydrogen electrode and kinetic current density of 51.9 mA cm(-2), significantly outperforming the commercial Pt/C. Both aqueous and all-solid-state zinc-air battery assembled with such catalyst demonstrate superior durability with little performance fluctuation, confirming their potential feasibility in the practical applications.
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