Post-Synthetic Modification of Metal-Organic Frameworks Toward Applications

Post-synthetic modification (PSM) of metal-organic framework (MOF) compounds is a useful technique for preparing new MOFs that can exhibit or enhance many of the properties of the parent MOFs. PSM can be carried out by a number of approaches such as modifying the linker (ligand) and/or metal node, and adsorption/exchange of guest species. The surface environment of the MOF can be modified to increase structural stability as well as introducing desired properties. There is considerable scope in widening the applications of the MOF with compatible metal or ligand employing the PSM. This review focuses on the recent developments of modified materials through PSM, which augers well for the chemical modification and functionalization of MOFs. In this review, different types of PSM methods are presented in an orderly manner, and the diverse applications of resultant frameworks are described and discussed.

Automated summary

Post-synthetic modification (PSM) is a useful technique for preparing new MOFs with enhanced properties by modifying linkers and metal nodes. Widening applications of MOFs with compatible metals or ligands through PSM shows considerable potential for introducing desired properties and increasing structural stability.