期刊
ADVANCED FUNCTIONAL MATERIALS
卷 30, 期 46, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202004748
关键词
degradation; electrolytes; lithium-ion batteries; Ni-rich cathodes; structures
类别
资金
- U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, and Vehicle Technologies Office
- DOE Office of Science by UChicago Argonne, LLC [DE-AC02-06CH11357]
Nickel-rich layered lithium transition metal oxides (LiNi(1-)(x)(-)(y)Co(x)Mn(y)O(2)and LiNi1-x-yCoxAlyO2,x +y <= 0.2) are the most attractive cathode materials for the next generation lithium-ion batteries for automotive application. However, they suffer from structural/interfacial instability during repeated charge/discharge, resulting in severe performance degradation and serious safety concerns. This work provides a comprehensive review about challenges and strategies to advance nickel-rich layered cathodes specifically for harsh (high-voltage, high-temperature, and fast charging) operations. Firstly, the degradation pathways of nickel-rich cathodes including surface/interface degradation, undesired cathode-electrolytes parasitic reactions, gas evolution, inter/intragranular cracking, and electrical/ionic isolation are discussed. Then, recent achievements in stabilizing the structure/interface of nickel-rich cathodes via surface coating, cation/anion doping, composition tailoring, morphology engineering, and electrolytes optimization are summarized. Moreover, challenges and strategies to improve the performance of Ni-rich cathodes at the electrode level are discussed. Outlook and perspectives to promote the practical application of nickel-rich layered cathodes toward automotive application are provided as well.
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