期刊
ACS NANO
卷 14, 期 9, 页码 11809-11820出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.0c04669
关键词
aqueous rechargeable zinc batteries; vanadium oxide; in operando X-ray diffraction; X-ray absorption spectroscopy; electrochemical properties
类别
资金
- National Natural Science Foundation of China [21773091, 51972140]
- Science and Technology Department of Jilin Province [20180414004GH, 20190103054JH]
- Education Department of Jilin Province [JJKH20200766KJ]
- Independent Industrial Innovation Funding of Jilin Province [2018C008]
- German Research Foundation (DFG) [390874152]
NH4+ preintercalated V2O5 center dot nH(2)O nanobelts with a large interlayer distance of 10.9 angstrom were prepared by the hydrothermal method. The material showed a large specific capacity of 391 mA.h.g(-1) at the 500 mA.g(-1) current density in aqueous rechargeable zinc batteries. In operando synchrotron X-ray diffraction demonstrated that the material experienced reversible solid-solution reaction and two-phase transition during charge-discharge cycling, accompanied by the reversible formation/decomposition of a ZnSO4Zn3(OH)(6)center dot 5H(2)O byproduct. In operando X-ray absorption spectroscopy confirmed the reversible reduction/oxidation of V, together with small changes in the VO6 local structure. The formation of byproduct was attributed to the dehydration of [Zn(H2O)(6)](2+), which concurrently improved the desolvation of [Zn(H2O)(6)](2+) into Zn2+. Bond valence sum map analysis and electrochemical impedance spectroscopy demonstrated that the byproduct improved the charge transfer kinetics of the electrode. Cyclic voltammetry and galvanostatic intermittent titration technique showed that the electrode reaction was dominated by ionic intercalation where the discharge capacity in the voltage window of 1.4-0.85 V was attributed to the intercalation of [Zn(H2O)(6)](2+), followed by the intercalation of Zn2+ at 0.85-0.4 V.
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