期刊
ACS APPLIED MATERIALS & INTERFACES
卷 12, 期 39, 页码 43824-43832出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c13437
关键词
solid-like electrolytes; metal-organic frameworks; open-metal sites; electrolytes beyond Li+; rechargeable batteries
资金
- UCLA-HK Center for Graphene Technology and Energy Storage
A new family of solid-like electrolytes was developed by infiltrating MIL-100(Al), an electrochemically stable metal-organic-framework (MOF) material, with liquid electrolytes that contain cations from the 3rd period (Na+, Mg2+, and Al3+) and the 1st group (Li+, Na+, K+, and Cs+). The anions were immobilized within the MOF scaffolds upon complexing with the open metal sites, allowing effective transport of the cations in the nanoporous channels with high conductivity (up to 1 mS cm-1) and low activation energy (down to 0.2 eV). This general approach enables the fabrication of superior conductive solid-like electrolytes beyond lithium ions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据