Fabrication of Nonmetal-Modulated Dual Metal-Organic Platform for Overall Water Splitting and Rechargeable Zinc-Air Batteries

The fast development of portable water-splitting devices has led to a great deal of work on rechargeable metal-air batteries or solar cells; however, the lack of affordable multifunctional electrocatalysts still hampers their widespread applications. Herein, a well-aligned ternary metal (oxy)hydroxide nanostructure is a sacrificial pseudomorphic transformation template of an integrated metal-organic network on the carbon cloth (CC) surface, that is, the Fe-doped metal-organic framework (MOF) ZnNiCoSe@CC nanosheet network, exhibiting powerful and efficient multifunctional electrocatalysts such as the oxygen reduction reaction, oxygen evolution reaction, and hydrogen evolution reaction in alkaline media combined with desirable electrode kinetics. As a proof-of-concept observational study, the nanostructured Fe-doped MOF ZnNiCoSe@CC could be used as air-cathode materials in the rechargeable metal-air battery. The fabricated device delivered higher open-circuit voltage, higher capacity, and peak power density, excellent discharge-charge performance, and long cycle life. Thus, our research creates a unique perspective on the development of highly portable air electrodes with a favorable electrocatalytic application of overall water-splitting reaction.