Functionalized NU-1000 with an Iridium Organometallic Fragment: SO2 Capture Enhancement

A new material, MOF-type [Ir]@NU-1000, was accessed from the incorporation of the iridium organometallic fragment [Ir-{kappa(3)(P,Si,Si)PhP(o-C(6)H(4)CH(2)Si(i)P(r)2)2}] into NU-1000. The new material incorporates less than 1 wt % of Ir(III) (molar ratio Ir to NU-1000, 1:11), but the heat of adsorption for SO2 is significantly enhanced with respect to that of NU-1000. Being a highly promising adsorbent for SO2 capture, [Ir]@NU-1000 combines exceptional SO2 uptake at room temperature and outstanding cyclability. Additionally, it is stable and can be regenerated after SO2 desorption at low temperature.