期刊
ISCIENCE
卷 23, 期 8, 页码 -出版社
CELL PRESS
DOI: 10.1016/j.isci.2020.101348
关键词
-
资金
- National Key Research and Development Program, China [2019YFA0210600]
- State Grid Shanghai Municipal Electric Power Company [520970190004]
- Innovative Research Groups of Hunan Province [2019JJ10001]
The highly reversible zinc-bromine redox couple has been successfully applied in the zinc-bromine flow batteries; however, non-electroactive pump/pipe/reser-voir parts and ion-selective membranes are essential to suppress the bromine diffusion. This work demonstrates a zinc-bromine static (non-flow) battery without these auxiliary parts and utilizing glass fiber separator, which overcomes the high self-discharge rate and low energy efficiency while the advantages of the zinc-bromine chemistry are well preserved. It is achieved by a multifunctional additive, tetrapropylammonium bromide (TPABr), which not only mitigates the bromine cross-diffusion by regulating the fluidic bromine to a condensed solid phase but also provides a favorable interface for zinc electrodeposition toward non-dendritic growth. The proposed zinc-bromine static battery demonstrates a high specific energy of 142 Wh kg(-1) with a high energy efficiency up to 94%. By optimizing the porous electrode architecture, the battery shows an ultra-stable cycling life for over 11,000 cycles with controlled self-discharge rate.
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