期刊
ACS APPLIED ENERGY MATERIALS
卷 3, 期 6, 页码 5439-5447出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.0c00297
关键词
nanocrystalline cobalt oxide; Co2+/Co3+ ratio; Co3+-O-h reducibility; OER kinetics; impedance study
资金
- Department of Science and Technology (DST)-Nanomission Thematic project [SR/NM/TP-25/2016]
- TEM Facility at CeNS under Nanomission Thematic project
- DST
- Sheikh Saqr Laboratory
- Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR)
- JNCASR
In Co3O4 systems, the oxygen vacancy is reported to improve the oxygen evolution reaction (OER) activity because of higher Co2+/Co3+ surface ratio. In situ studies have revealed Co3+-site reducibility as the key factor for OER activity of cobalt oxide-based systems. In this context, we have synthesized and analyzed OER activity of two Co3O4 systems; c-Co3O4 with higher oxygen defects or Co2+/Co3+ ratio and n-Co3O4 with relatively less Co2+/Co3+ ratio but more Co3+ reducibility. The systems, n- and c-Co3O4 show overpotential of 380 and 440 mV at 10 mA/cm(2) and Tafel slope of 153 and 53 mV/dec, respectively, for OER. Electrochemical characterization reveals that the lowering of OER onset potential is influenced by Co3+ reducibility rather than defects in Co3O4 systems while adsorption capacitance arising from surface irregularities, pores and their geometry, and Co3+-O-h sites cause an increase in the Tafel slope values or decrease in OER kinetics. The correlation of the key factors such as Co3+ reducibility and oxygen defects of two different Co3O4 systems toward OER activity can aid the designing of highly efficient cobalt oxide-based OER catalysts.
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