期刊
ACS APPLIED ENERGY MATERIALS
卷 3, 期 5, 页码 4208-4216出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.9b02191
关键词
ethylene glycol; graphene; atomic layer deposition; electron transport layer; flexible perovskite solar cell; power conversion efficiency; transmittance
资金
- National Natural Science Foundation of China [61974054, 61675088, 61275024, 61377026]
- International Science & Technology Cooperation Program of Jilin [20190701023GH]
- International Science & Technology Cooperation Program of China [2014DFG12390]
- National Key Research Program of China [2016YFB0401001]
- Scientific and Technological Developing Scheme of Jilin Province [20140101204JC, 20130206020GX, 20140520071JH, 20130102009JC]
- Project of Science and Technology Development Plan of Jilin Province [20190302011G]
- Opened Fund of the State Key Laboratory on Integrated Optoelectronics [IOSKL2016KF08]
Graphene is a promising electrode for the flexible perovskite solar cells (PSCs), whereas electron transport layer (ETL) oxides, prepared by atomic layer deposition (ALD), render high performance in PSCs. However, the growth of ALD oxides on surface-inert graphene remains a challenging task. Herein, we demonstrate that a viscous precursor of molecular layer deposition (MLD) ethylene glycol (EG) endows active sites to the graphene surface by the strong van der Waals forces and realizes the ALD of high-performance oxides for next-generation flexible PSCs. The EG-functionalized graphene surface is utilized to deposit an ALD-ZnO film, which renders high transmittance, low-energy levels, and superior electron injection capability. Moreover, the power conversion efficiency (PCE) of EG-graphene/ZnO-based PSCs is 133.9% higher than graphene/ZnO-based PSCs, and they retained 92.2% of the initial PCE after 1000 bending cycles. This method opens up alternate avenues to improve the flexible PSCs and other flexible optical electronics.
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