期刊
SOLAR RRL
卷 4, 期 10, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/solr.202000253
关键词
core units; grazing-incidence X-ray scattering; morphologies; organic solar cells; small-molecule acceptors
资金
- Center for Emergent Functional Matter Science of National Chiao Tung University from the Featured Areas Research Center Program within Ministry of Education (MOE) in Taiwan
- Ministry of Science and Technology, Taiwan [MOST 107-2923-M-009-004-MY3, MOST 109-2221-E-009-064-MY3]
Understanding the chemical structures of next-generation small molecules is a critical step for increasing the performance of organic photovoltaics (OPVs); an OPV's small molecule determines not only the extent of light absorption but also the morphology. Herein, four small molecules featuring different cores-indaceno dithiophene, dithienoindeno indaceno dithiophene (IDTT), substituted IDTT, and dithienothiophene-pyrrolobenzothiadiazole-denoted as ID-4Cl, IT-4Cl, m-ITIC-OR-4Cl, and Y7, respectively, are selected to form active layers with poly(quinoxaline) (PTQ10) and poly(benzodithiophene-4,8-dione) (PM6). The Y7 devices exhibit the best performance in both systems, with the power conversion efficiency (PCE) reaching 14.5%; in comparison, ID-4Cl device gives a PCE of 10.0% for blending with PTQ10 and a relative efficiency enhancement of 45%. The same trend occurs for the cases of PM6 blend devices. This enhancement is attributed to i) the improved short-circuit current density that is provided by the greater degree of conjugation in S, N-heteroarenes ladder-type fused-ring cores of Y7, ii) an induced face-on Y7 orientation and smaller domain sizes that result from the sp(2)-hybridized nitrogen side chain, and iii) smaller energy loss. This study reveals the importance of the core structure on the device performance and provides guidelines for the design of new materials for OPV technologies.
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