期刊
ENERGY STORAGE MATERIALS
卷 27, 期 -, 页码 316-326出版社
ELSEVIER
DOI: 10.1016/j.ensm.2020.02.020
关键词
NiCoP@NiCoP; TiN@Fe2O3; Hierarchical core-shell heterostructure; Fiber-shaped NiCo//Fe battery; Wearable electronics
资金
- National Natural Science Foundation of China [51703241]
- Fundamental Research Funds for the Central Universities [020514380183]
- Key Research Program of Frontier Science of Chinese Academy of Sciences [QYZDB-SSW-SLH031]
- Thousand Youth Talents Plan
- Science and Technology Project of Nanchang [2017-SJSYS-008]
The rational design and construction of high-performance fiber-shaped NiCo//Fe batteries is of great importance for the development of portable and wearable electronics. Electrode materials with all hierarchical core-shell heterostructures have great potential for use in high-performance NiCo//Fe batteries as a result of their good conductivity, high mass loading, and short ion-diffusion paths. Herein is proposed a novel freestanding core-shell positive and negative electrode materials developed by depositing NiCoP nanosheets on nanoflake arrays (NiCoP@NiCoP NFAs) and Fe2O3 nanoneedles on TiN nanowire arrays (TiN@Fe2O3 NWAs) directly grown on carbon nanotube fibers (CNTFs). The fabricated NiCoP@NiCoP NFAs/CNTF was validated to be an ultrahigh capacity cathode (1.07 mAh cm(-2) at 2 mA cm(-2)), matching well with the similarly constructed TiN@Fe2O3 NWAs/CNTF anode (0.92 mAh cm(-2) at 2 mA cm(-2)). These electrodes were successfully developed into a high-performance NiCo//Fe battery that exhibited an extraordinary capacity of 0.77 mAh cm(-2) and a remarkable energy density of 265.2 mWh cm(-3). The flexible battery demonstrated an excellent cycling lifespan with 89.4% capacity retention after 4000 cycles. This pioneering study describes a powerful strategy for the rational construction of high-performance electrode materials with hierarchical core-shell heterostructures and constitutes a novel approach for the development of new-generation wearable aqueous rechargeable batteries.
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