期刊
CHEMISTRYSELECT
卷 5, 期 26, 页码 7822-7825出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202002247
关键词
C=C cleavage; alpha-diazoketone; enaminone; in water; microwave
资金
- National Natural Science Foundation of China [21861019, 21562025]
The reactions of enaminones with methyl sulfonyl azide providing alpha-diazoketones have been realized in pure water by means of microwave irradiation. Besides the green medium and energy source, the reactions benefit additional advantages of sustainability from the totally catalyst- and additive-free conditions. More significantly, the synthesis remarks the first successful application of the featured tandem [3+2] cyclo-addition and subsequent ring decomposition of the in situ generated 1,2,3-triazoline intermediate from enaminones and sulfonyl azide in the synthesis of alpha-diazoketones.
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