期刊
SCIENCE BULLETIN
卷 65, 期 20, 页码 1726-1734出版社
ELSEVIER
DOI: 10.1016/j.scib.2020.05.031
关键词
Perovskite solar cell; Surface passivation; Chemical bonding; Functional groups; Hydrogen bonding
资金
- Research Grants Council of Hong Kong [T23-407/13-N]
- Innovation and Technology Commission [ITS/088/17]
- Central Organization Department
- Guangdong Science and Technology Program [2020B121201003]
- National Natural Science Foundation of China [21776315]
- PetroChina Innovation Foundation [2017D5007-0402]
- Pearl River Talent Program [2019ZT08L075, 2019QN01L118]
- Fundamental Research Funds for the Central Universities [19CX05001A]
- South China University of Technology
Many organic molecules with various functional groups have been used to passivate the perovskite surface for improving the efficiency and stability of perovskite solar cell (PSCs). However, the intrinsic attributes of the passivation effect based on different chemical bonds are rarely studied. Here, we comparatively investigate the passivation effect among 12 types of functional groups on para-tertbutylbenzene for PSCs and find that the open circuit voltage (V-OC) tends to increase with the chemical bonding strength between perovskite and these passivation additive molecules. Particularly, the paratert-butylbenzoic acid (tB-COOH), with the extra intermolecular hydrogen bonding, can stabilize the surface passivation of perovskite films exceptionally well through formation of a crystalline interlayer with water-insoluble property and high melting point. As a result, the tB-COOH device achieves a champion power conversion efficiency (PCE) of 21.46%. More importantly, such devices, which were stored in ambient air with a relative humidity of similar or equal to 45% can retain 88% of their initial performance after a testing period of more than 1 year (10,080 h). This work provides a case study to understand chemical bonding effects on passivation of perovskite. (C) 2020 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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