期刊
CURRENT OPINION IN CHEMICAL ENGINEERING
卷 28, 期 -, 页码 43-50出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.coche.2020.01.004
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The modeling description of basic transport phenomena of either liquid, gas or vapor molecules in dense polymeric membranes is of tremendous impact for the separation industry, which relies on solid models for the design of optimal process conditions, for the selection of the most suitable membrane materials as well as for the development of novel ones. Such models need to deal with several physical aspects and phenomena, spanning over broad time and length scales, thus requiring multiple approaches. The solid frameworks now available mainly rely on the solution-diffusion theory, in which equation of state models and free volume theories are applied for the description of thermodynamic and kinetic properties, to be coupled in appropriate transport schemes.
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