Quantum-Sized Zinc Oxide Nanoparticles Synthesised within Mesoporous Silica (SBA-11) by Humid Thermal Decomposition of Zinc Acetate

A modified facile method is presented to synthesise quantum-sized zinc oxide nanoparticles within the pores of a mesoporous silica host (SBA-11). This method eliminates the 3 h alcohol reflux and the basic solution reaction steps of zinc acetate. The mesoporous structure and the ZnO nanoparticles were analysed by X-ray diffractometry, transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, nitrogen sorption analysis and UV-VIS spectroscopy. These tests confirm the synthesis of similar to 1 nm sized ZnO within the pores of SBA-11 and that the porous structure remained intact after ZnO synthesis.