期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 506, 期 -, 页码 694-702出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2016.07.047
关键词
Electrodeposition; FeCoNi compound; Oxygen evolution catalyst; Nickel foam; Water electrolysis
资金
- National Natural Science Foundation of China [21103134, 21505102]
- Shaanxi Provincial Natural Science Foundation of China [2016JM2008]
- Key Laboratory of Applied Surface and Colloid Chemistry (Shaanxi Normal University)
It is very important to develop efficient and stable oxygen evolution catalyst with low-cost and earth abundant elements for large scale hydrogen production from water electrolysis. In this article, a ternary FeCoNi oxygen evolution catalyst was prepared by simple electrodeposition on nickel foam. The composition and structure of the catalyst was characterized by SEM, TEM, XRD and XPS. The performance of the catalyst was measured in alkaline solution. The results show that the ternary catalyst has behaved high activity and stability for water electrolysis. The onset overpotential is as low as 0.20 V (vs. RHE) and the overpotential is as low as 0.37 V (vs. RHE) at the high current density of 300 mA/cm(2) when the catalyst was employed as an anode for water electrolysis. Moreover, the stability of the anode is very good at high current density. The potential retains at almost the same value after more than 8 h continuous electrolysis and the SEM measurement confirms that the catalyst was not decomposed or exfoliated from the nickel foam. (C) 2016 Elsevier B.V. All rights reserved.
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