期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 8, 期 34, 页码 13076-13084出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.0c04862
关键词
Glycerol ethers; DES; Green solvents; Pd-NPs; Heck-Mizoroki; IL
资金
- Ministerio de Ciencia, Innovacion y Universidades [RTI2018-093431-B-I00]
- Gobierno de Aragon [E37 20R]
- European Regional Development Funds
- MECD [FPU14/04338]
Glycerol-derived ethers and their eutectic mixtures with two renewable ammonium salts (ChCl and N00Cl) are effectively used as new green solvents for the immobilization of PVP-Palladium nanoparticles. Those air-stable, selective, and recoverable catalytic systems are applied in the benchmark Heck-Mizoroki coupling reaction between iodobenzene and n-butyl acrylate in order to evaluate the influence of the different solvation properties of the solvent on the reaction results. The HBD ability (alpha acidity) of the solvent seems to play a crucial role in the reaction selectivity.
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