期刊
ACS CATALYSIS
卷 10, 期 18, 页码 10546-10550出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c02716
关键词
photocatalysis; hybrid catalysis; Bronsted base; malonates; radical process
资金
- Japan Agency for Medical Research and Development (AMED)
- Japan Society for the Promotion of Science (JSPS) KAKENHI [17H06448]
- Grants-in-Aid for Scientific Research [17H06448] Funding Source: KAKEN
Bronsted base-photocatalyst hybrid systems have been developed for reactions of malonates with styrene derivatives. The concept of this process lies in the photo-oxidation of catalytic amounts of the enolate to form reactive radicals that react with alkene double bonds under mild reaction conditions. This is an example of visible-light-activated C-C bond formation reactions of malonates with alkenes to realize high atom economy under very mild reaction conditions without using any transition-metal catalysts.
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