期刊
TOXIN REVIEWS
卷 40, 期 4, 页码 835-846出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/15569543.2020.1790606
关键词
Cr(VI); decontamination; cellulose; adsorption; wastewater treatment
类别
资金
- Deanship of Scientific Research at King Khalid University [GRP-211-41]
The study demonstrated that chemically modified sugarcane bagasse cellulose has high removal efficiency for Cr(VI) in aqueous solutions, reaching nearly 100% removal after 180 minutes. The adsorption process of CST for Cr(VI) fits well with the pseudo-second-order kinetic model and Langmuir isotherm model.
The hexavalent chromium (Cr(VI)) reported severe threat to the environment and public health as it is considered potentially mutagenic and carcinogenic. This communication demonstrates a chemical modification process of sugarcane bagasse cellulose for the removal of Cr(VI) from aqueous solutions. Cellulose was extracted from sugarcane bagasse followed by succination to form cellulose succinate (CS), which was then reacted with acetic anhydride to form cellulose succinic anhydrides (CSA). The latter was then reacted with triethylenetetramine (TETA) to form CS-TETA (CST). The prepared CST was characterized by Fourier transform infrared spectrometry (FTIR), scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDX), and Brunauer-Emmett-Teller (BET) analyzer. The maximum removal efficiency of Cr(VI) by CST reached nearly 100% after 180 min, which was obtained at pH 1.0. The adsorption process fit well with the pseudo-second-order kinetic model, while the rate constant was 9.13 x 10(-3 )g/mg min. The isothermal study showed that the results closely aligned with the Langmuir isotherm model and the maximum adsorption capacity was 12.4 mg/g.
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