期刊
SYNTHESIS-STUTTGART
卷 52, 期 17, 页码 2450-2468出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707814
关键词
heterocycles; atropisomerism; organocatalysis; indole; pyrrole; pyridine; quinoline
A perspective on the literature dealing with the organocatalytic asymmetric preparation of axially chiral N-heterocycles is provided. A particular focus is devoted to rationalize the synthetic strategies employed in each case. Moreover, specific classes of organocatalysts are shown to stand out as privileged motives for the stereoselective preparation of such synthetically challenging molecular architectures. Finally, an overview of the main trends in the field is given.
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