期刊
SYNTHESIS-STUTTGART
卷 52, 期 17, 页码 2469-2482出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707160
关键词
hexahydro-1,3,5-triazines; 1,3,5-triazinanes; formald-imines; aminomethylations; cycloadditions; nitrogen-containing compounds
资金
- National Natural Science Foundation of China [91856119, 21820102003, 91956201, 21772053]
- Plan 111 (Program of Introducing Talents of Discipline to Universities of China, 111 Program) [B17019]
1,3,5-Trisubstituted 1,3,5-triazinanes (hexahydro-1,3,5-triazines), as stable and readily available surrogates for formaldimines, have found extensive applications for the construction of various nitrogen-containing compounds. The formaldimines, formed in situ from this reagent class, can participate in various aminomethylation and cycloaddition- reactions. This short review presents recent advances in this field with emphasis on the conceptual ideas behind the developed methodologies and the reaction mechanisms.
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