期刊
SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 210, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.solmat.2020.110500
关键词
Multi-junction solar cells; GaAsSbN; Superlattices; Type-II band Alignment; Strain-balanced; 1 eV bandgap
资金
- Spanish MINECO [MAT2016-77491-C2-1-R]
- CSIC [EUIN2017-88844, RYC-2017-21995]
- Comunidad de Madrid [P2018/EMT-4308]
- EU COST Action [MP1406]
We demonstrate type-II GaAsSb/GaAsN superlattices (SL) as a suitable structure to form the lattice-matched 1.0-1.15 eV subcell that would allow the implementation of the optimum monolithic multi-junction solar cell design. The separation of Sb and N atoms during growth leads to an improved composition homogeneity and a lower defect density than in the bulk GaAsSbN counterparts. The type-II band alignment SLs provide long radiative lifetimes that facilitate carrier collection as compared to equivalent type-I SLs. Moreover, the radiative lifetime can be controllably tuned through the period thickness, which is not possible in type-I SLs. A reduced period thickness results in enhanced absorption due to increased wavefunction overlap, as well as in a change in the transport regime from diffusive to quasiballistic, providing improved carrier extraction efficiency. As a result, the short period SL single junction solar cells show an enhanced power conversion efficiency of 134% over the equivalent bulk devices.
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