4.4 Article

Separation of Cd(II), Cu(II) and zinc sulfate from waste produced in zinc hydrometallurgy cementation

期刊

SEPARATION SCIENCE AND TECHNOLOGY
卷 56, 期 8, 页码 1360-1369

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2020.1780446

关键词

Metal separation; hazardous waste; aqueous two-phase system; metal recuperation; environmentally safe technique

资金

  1. Conselho Nacional de Desenvolvimento Cientifico e Tecnologico [425913/2018-0]
  2. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior [001]
  3. Fundacao de Amparo a Pesquisa do Estado de Minas Gerais [APQ-01308-18]

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The study successfully utilized ATPS to extract Cu(II) and Cd(II) while concentrating zinc (II) in the bottom phase.
This study aims to evaluate the feasibility of applying aqueous two-phase systems (ATPS) to process the zinc hydrometallurgical cementation residue, seeking to extract the Cu(II) and Cd(II) in the top phase, while zinc is concentrated in the bottom phase. Initially, leaching conditions were optimized. After evaluating several polymers, the optimum conditions of ATPS formation were: poly(ethylene glycol) 4000 g.mol(-1)at 18 wt% and pH = 2.0. After two extraction steps, high values of %E for Cu(II) (%E = 90.1 +/- 3.1%) and Cd(II) (%E = 99.1 +/- 4.0%) were obtained, while Zn(II) was predominantly retained in the bottom phase.

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