期刊
RENEWABLE ENERGY
卷 162, 期 -, 页码 242-248出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.renene.2020.07.111
关键词
Lignocellulose; Platform chemicals; Process design; Process economics; Optimization; Optimal operation
资金
- National Research Foundation of Korea (NRF) - Korean government (MSIT) [2018R1C1B6009074]
- National Research Foundation of Korea [2018R1C1B6009074, 5199991614567] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We propose an integrated strategy for the production of vital platform chemicals, levoglucosenone (LGO) and 5-hydroxymethylfurfural (HMF), used to produce a high-value chemical, 1,6-hexandiol, from lignocellulosic biomass. In such processes of producing essential chemicals from biomass, cellulose loading in the solvent has a significant impact on production yield and, consequently, the economics of the process. In this study, we compare four different loadings of 1, 3, 5, and 10 wt% to suggest the optimal cellulose loading in tetrahydrofuran. The integrated process is economically optimal at a cellulose loading of 5 wt%. The minimum selling price (MSP) of the LGO and HMF mixture is estimated to be $2387/ton, which is competitive compared with the previously reported MSP of $2920/ton (He et al. Green Chemistry,19, 3642-3653, 2017), at the optimal loading of 5 wt%. (c) 2020 Elsevier Ltd. All rights reserved.
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