期刊
RARE METALS
卷 40, 期 7, 页码 1971-1978出版社
NONFERROUS METALS SOC CHINA
DOI: 10.1007/s12598-020-01503-4
关键词
Lithium-ion batteries; Hydrochloric acid; Ammonium chloride; Chlorine gas
资金
- National Key Research and Development Program [2018YFB0605702]
- National Natural Science Foundation of China [51774260, 21606241, 51804289]
- Key Research Program of Frontier Sciences of Chinese Academy of Sciences
- CAS Interdisciplinary Innovation Team
This study experimentally investigated the effects of NH4Cl, HCl, and reductants on metal extraction from spent lithium-ion batteries. It was found that adding solid NH4Cl to an HCl solution improved metal extraction capability and reduced chlorine gas formation significantly. Activation energies for leaching Li, Ni, Co, and Mn were determined, providing insights into an environmentally friendly recycling method for metal resources.
This study focused on the extraction of valuable metals from the cathode-active materials in spent lithium-ion batteries using a high-concentration chloride solution. The effects of the concentrations of ammonium chloride (NH4Cl), hydrochloric acid (HCl), and reductants such as hydrogen peroxide (H2O2) and urea (CO(NH2)(2)) on metal extraction and chlorine production were studied experimentally. The leaching mechanism was analyzed, and a leaching model was established. It was found that the addition of solid NH4Cl to an HCl solution significantly improved the metal extraction capability of the latter and reduced the formation of chlorine gas by 96.0% compared to that only using HCl. The activation energies for leaching Li, Ni, Co, and Mn were determined to be 30.4, 38.5, 30.6, and 38.2 kJ center dot mol(-1), respectively. This study demonstrates an environmentally friendly method for recycling metal resources from cathode-active materials and furthers understanding of how NH4Cl inhibits chlorine production when leaching with mixed solutions of HCl and NH4Cl.
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