期刊
PROCEEDINGS OF THE COMBUSTION INSTITUTE
卷 38, 期 1, 页码 355-364出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.proci.2020.06.012
关键词
Urea; Pyrolysis; Theoretical; Isocyanuric acid; Kinetic model
Urea is commonly used in post-combustion processes for NOx reduction, where its decomposition can lead to the formation of NH3 as the reducing agent. However, undesirable pyrolysis by-products can also be produced, especially under suboptimal temperature and pressure conditions. This study proposed a gas phase kinetic model for urea pyrolysis, revealing a new mechanism for the formation of isocyanuric acid through carbamimidic acid and biuret intermediates. The proposed mechanism was validated through experimental conditions and simulations in both gas phase and pseudo condensed phase systems.
Urea is used in Selective Catalytic and Non Catalytic Reduction (SCR and SNCR) methods for NOx abatement in post-combustion processes. The decomposition of urea-water solution in exhaust systems leads to the formation of NH3, which is the NOx reducing agent. However, the decomposition of urea can also lead to the formation of unwanted pyrolysis by-products, particularly in region where the temperature and pressure conditions are not optimal or via wall-spray interactions. In this study, a gas phase kinetic model for urea pyrolysis is proposed to explain the growth of pyrolysis by-products of urea, and in particular, the route of formation of the major product: isocyanuric acid. Systematic theoretical calculations, using electronic structure calculations and transition state theory, were performed to explore all the possible unimolecular and bimolecular reactions of the initial species. Kinetic modeling was used to select the relevant reaction pathways at each growing step, and their rate constants were refined using CCSD(T)/CBS//B2PLYP-D3/cc-pvTZ calculations. Quantum calculations showed that the postulated growing schemes of the literature, based on the successive urea + HNCO reversible arrow biuret, biuret + HNCO reversible arrow triuret followed by the cyclization of triuret into isocyanuric acid are not energetically favored. It is observed that the most favored reaction route to isocyanuric acid involves carbamimidic acid, the urea tautomer, that first yields biuret in a reaction with HNCO and then is involved in the formation of triuret by reacting with a decomposition product of biuret. Isocyanuric acid is produced from the reaction between HNCO and the same decomposition product of biuret. This new mechanism of formation of isocyanuric acid is tested at different conditions to explore its most favored conditions of formation in the gas phase. Exploratory simulations of a pseudo condensed phase are also performed to qualitatively simulate condensed phase experiments and explain the observed pyrolysis yields. (c) 2020 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
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