期刊
POLYMER
卷 202, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2020.122740
关键词
Liquid crystalline polymer; Phase behavior; Self-assembly; Application
资金
- National Key R&D Program of China [2018YFB0703702]
- National Natural Science Foundation of China [51725301, 51921002]
Liquid crystalline polymers (LCPs) have drawn much interest because of their superior properties and widespread applications in high-performance polymer fibers, optics, energy storage, shape memory, surface modification, data storage, actuator, etc. LCPs can self-assemble into various liquid crystalline (LC) phases, such as nematic, smectic, columnar, and cholesteric phases. The self-assembling structures of LCPs can be influenced by architectures and chemical structures of the polymer backbone, mesogenic unit, flexible spacer, surrounding alkyl tail, etc. In the last decades, the structure-property relationships of LCPs have been researched extensively. In this perspective, the history, self-assembly, and applications of main-chain, side-chain, mesogen-jacketed, dendronized, main-chain/side-chain, and crosslinked LCPs are briefly reviewed. Finally, the future direction of research on LCPs is also discussed.
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