期刊
ORGANIC LETTERS
卷 22, 期 15, 页码 5915-5919出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02012
关键词
-
资金
- JSPS KAKENHI [JP 17J00349, JP 15H05485, JP 18K19078, JP 17H06092]
- Kyoto Technoscience Center
A copper-mediated, phenanthroline-directed highly ortho-selective C-H sulfenylation of phenols with diaryl disulfides proceeds to form the corresponding unsymmetrical diaryl sulfides in good yield. The key to success is the introduction of a phenanthroline directing group of the bidentate-chelating nature, which is easily attachable, detachable, and even recyclable. Moreover, the same strategy is applicable to the C-H selenation, giving the diaryl selenides with high efficiency and regioselectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据