期刊
ORGANIC LETTERS
卷 22, 期 16, 页码 6244-6247出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01890
关键词
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资金
- JSPS KAKENHI [JP19K07006]
- Takahashi Industrial and Economic Research Foundation (public interest incorporated foundation) [10-003-181]
A novel method was developed for the synthesis of tetrazoles from amides utilizing diphenyl phosphorazidate or bis(p-nitrophenyl) phosphorazidate as both the activator of amide-oxygen for elimination and azide source. Various amides were converted into the corresponding tetrazoles in good yields. This synthetic method allows to prepare 1,5-disubstituted and 5-substituted 1H-tetrazoles from various amides without the use of toxic or explosive reagents.
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