期刊
ORGANIC LETTERS
卷 22, 期 13, 页码 5025-5029出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01582
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资金
- TU Braunschweig
The intra- and intermolecular synthesis of selenium-substituted acyclic and heterocyclic acrylonitrile derivatives is presented. The 1,2-difunctionalization of several internal alkynes substituted not only by aliphatic and aromatic residues but also by heteroelements is realized by the Pd-catalyzed activation of aromatic and aliphatic selenocyanates. A high functional group tolerance allows straightforward access to a broad scope of tetrasubstituted olefins. X-ray studies of some products reveal noncovalent chalcogen-chalcogen interactions between oxygen and selenium.
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