期刊
ORGANIC LETTERS
卷 22, 期 14, 页码 5347-5352出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01592
关键词
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资金
- National Natural Science Foundation of China [21772183]
- Fundamental Research Funds for the Central Universities [WK2060190086]
- 1000-Youth Talents Plan start-up funding
- University of Science and Technology of China
Herein we successfully applied Katritzky salts as the alkyl electrophile in the reductive allylic defluorinative cross-coupling reaction with alpha-trifluoromethyl alkenes. The merger of C-F and C-N bond cleavage via the synergistic effect of nickel and zinc allows the efficient synthesis of diverse gem-difluor-oalkenes with a good tolerance for various functional groups.
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