期刊
ORGANIC LETTERS
卷 22, 期 12, 页码 4888-4892出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01735
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资金
- JSPS KAKENHI [15H05755, 15H05810, 19K15560]
- Program for Leading Graduate Schools IGER program in Green Natural Sciences
- Grants-in-Aid for Scientific Research [15H05810, 15H05755, 19K15560] Funding Source: KAKEN
The halogen-bonding interaction between I-2 and N-iodosuccinimide (NIS) stabilized by a Lewis base (LB) has been explored. H-1 NMR, nuclear Overhauser effect (NOE), and diffusion-ordered NMR spectroscopy (DOSY) suggest the generation of a 1 : 1 : 1 assembly, LB-I-2-NIS. In contrast, when N-iodotrifluoromethanesulfonimide (INTf2) is used instead of NIS, LB-I-5(+)-LB is generated. On the basis of these results in combination with density functional theory (DFT) calculations, we propose a mechanism for the formation of I-2-NIS and the subsequent generation of an active iodinating species LB-I+.
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