期刊
MOLECULES
卷 25, 期 14, 页码 -出版社
MDPI
DOI: 10.3390/molecules25143227
关键词
multicomponent reactions; Passerini reaction; diastereoselective reactions; lipase; desymmetrization; Michael reaction; bio-based; biomass
A chiral bio-based building block, prepared by the lipase-mediated desymmetrization of an erythritol derivative, was further functionalized and then submitted to stereoselective Passerini reactions, allowing the synthesis of a small library of new molecules. Thanks to the presence of different functional groups, further cyclizations were performed providing bicyclic polyoxygenated heterocycles.
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