期刊
MOLECULES
卷 25, 期 12, 页码 -出版社
MDPI
DOI: 10.3390/molecules25122942
关键词
targeted LC-HRMS analysis; turmeric characterization; polyphenols; curcuminoids; principal component analysis; partial least squares-discriminant analysis
资金
- Spanish Ministry of Science and Innovation [PGC2018-095013-B-I00]
- Agency for Administration of University and Research Grants (Generalitat de Catalunya) [2017SGR-171, 2017SGR-310]
The importance of monitoring bioactive substances as food features to address sample classification and authentication is increasing. In this work, targeted liquid chromatography coupled to high-resolution mass spectrometry (LC-HRMS) polyphenolic and curcuminoid profiles were evaluated as chemical descriptors to deal with the characterization and classification of turmeric and curry samples. The profiles corresponding to bioactive substances were obtained by TraceFinder(TM)software using accurate mass databases with 53 and 24 polyphenolic and curcuminoid related compounds, respectively. For that purpose, 21 turmeric and 9 curry samples commercially available were analyzed in triplicate by a simple liquid-solid extraction procedure using dimethyl sulfoxide as extracting solvent. The obtained results demonstrate that the proposed profiles were excellent chemical descriptors for sample characterization and classification by principal component analysis (PCA) and partial least squares-discriminant analysis (PLS-DA), achieving 100% classification rates. Curcuminoids and some specific phenolic acids such astrans-cinnamic, ferulic and sinapic acids, helped on the discrimination of turmeric samples; polyphenols, in general, were responsible for the curry sample distinction. Besides, the combination of both polyphenolic and curcuminoid profiles was necessary for the simultaneous characterization and classification of turmeric and curry samples. Discrimination among turmeric species such asCurcuma longavs.Curcuma zedoaria, as well as among differentCurcuma longavarieties (Alleppey, Madras and Erode) was also accomplished.
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