期刊
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
卷 51, 期 5, 页码 2119-2130出版社
SPRINGER
DOI: 10.1007/s11663-020-01915-8
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资金
- National Natural Science Foundation of China [51974133, 51774141]
- Natural Science Foundation of Hebei Province of China [E2019209543, E2018209195]
- National Youth Natural Science Foundation of China [51904107]
Herein, the effects of BaO (i.e. 5, 10, 15 and 20 pct) on the viscosity and structures of a new fluorine-free CaO-Al2O3-TiO2-based mold flux with w(CaO pct)/w(Al(2)O(3)pct) ratio of 1.0 are investigated using a rotary viscometer, molecular dynamics (MD) simulations, and Raman spectroscopy. The viscosity of the samples (the testing temperature is 1300 degrees C) decrease from 0.46 to 0.21 Pa center dot s as the BaO content increased from 5 to 20 pct, and the activation energy decreases from 150.7 to 119.7 kJ center dot mol(-1), the break temperature (T-br) decreases from 1475 K to 1429 K which are achieved as the initial testing temperature of 1300 degrees C decreased under the furnace cooling. With the addition of BaO, the MD simulation results suggest that the coordination numbers (CNs) of Al (Ti)-O are reduced, while Q(3), Q(4), and Q(5)are depolymerized into Q(0), Q(1), and Q(2). The Raman spectroscopy results illustrate that the bridge oxygens (BOs) originating from the Ti-O-Ti (Al) linkages and Q(2)(Al-O-) are depolymerized into Q(1)(Si-O-) and Q(0)(Al-O-) as the BaO content is increased. The Raman spectroscopy results agree well with those of the MD simulation. Therefore, BaO can simplify the structure of melts and decrease the viscosity of such systems. This work not only presents a new fluorine-free CaO-Al2O3-TiO2-based mold flux, but also deepens the understandings of the role of BaO in this system.
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